block: fix bad definition of BIO_RW_SYNC

We can't OR shift values, so get rid of BIO_RW_SYNC and use BIO_RW_SYNCIO
and BIO_RW_UNPLUG explicitly. This brings back the behaviour from before
213d9417

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Signed-off-by: Jens Axboe <jens.axboe@oracle.com>